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The cathedral is the oldest in all of Tuscany (6th-century), although the architecture is predominantly Romanesque. A small museum next door has a few beautiful choir books. The bell tower outside is of medieval construction.
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Chiusi was a major Etruscan center and this museum has numerous Etruscan artifacts (many urns!), many of which display the Greek influence on the Etruscans. This one of the most important repositories of Etruscan remains in Italy. A nice way to spend twenty minutes.