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Photo: Halley Pacheco de Oliveira, CC BY-SA 3.0 via Wikimedia Commons
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Igreja de São Francisco de Paula, Old Cathedral of Rio de Janeiro
Igreja de São Francisco da Penitência
Colonial church built in 1773.
Convento de Santo Antônio Igreja da Venerável Ordem Terceira de São Francisco da Penitência
Church of the Venerable Third Order of St. Francis of Penance is a part of the Convent of Saint Antony
The headquarters for the federal gas (petrol) company is an interesting piece of brutalist architecture which somehow resembles a Rubik's Cube with some blocks missing.